Poly[(μ2-4,4′-bipyridine)bis­(μ4-5-tert-butyl­isophthalato)bis­(μ3-5-tert-butyl­isophthalato)di-μ3-hydroxido-penta­zinc(II)]

摘要

The asymmetric unit of the title compound, [Zn5(C12H12O4)4(OH)2(C10H8N2)]n, consists of three ZnII ions (one of which is located on a twofold rotation axis), two 5-tert-butyl­isophthalate ligands, one 4,4′-bipyridine ligand and one hydroxide group. The five ZnII ions form a penta­nuclear zinc cluster, which is further bridged by ten organic ligands, forming two-dimensional sheets. The central zinc ion of the cluster has site symmetry 2 and is octahedrally coordinated in a N2O4 donor set, whereas the other four zinc atoms are tetrahedrally coordinated by four O atoms. The coordination modes for the 5-tert-butyl­isophthalates are bis­(bidentate) or bidentate-monodentate. Hydrogen bonds are formed between adjacent sheets through the hydroxide groups and the O atoms of the monodentate carboxyl­ate groups. The two tert-butyl groups are disordered over two positions with ratios of 0.64 (2):0.36 (2) and 0.85 (3):0.15 (3).